Free White Paper

Pinpointing Polypropylene Glass Transition Temperatures Using Sub-Zero Rheology

More precise than DSC. Faster than DMA.

Learn how a sub-zero rheology approach delivers more precise Tg measurements than traditional DSC, and faster readings than DMA, in minutes.

In this white paper, you’ll learn:

Get the white paper

Download the polypropylene glass-transition white paper.

We use your details to send this download and related information. See our privacy policy.
+/-0.5 °C

Tg sensitivity between grades

Minutes

instead of hours or days

No liquid N₂

sub-ambient testing without cryogenics

The Challenge

Why you need a more accurate way to measure PP Tg

Polypropylene’s versatility comes from its low cost and ease of processing, but its real-world performance at sub-ambient temperatures depends on its glass transition temperature (Tg), which varies subtly between grades.

Traditional Tg measurements with DSC or DMA can be slow, less accurate in the case of DSC, and impractical for routine QC. A fully encapsulated sub-zero rheometer reduces slippage and variance, delivering highly repeatable, rapid measurements free from human error.

Rapid, High-Precision Tg Profiling

Tg insights in minutes, not hours or days

A next-generation sub-zero rheometry workflow helps you make confident material choices faster.

Test faster

Replace slow, multi-step DSC or DMA routines with a single test, so R&D and QC teams can focus on innovation instead of backlogs.

Precision without cryogenics

Distinguish Tg shifts as small as 0.5 °C without liquid nitrogen.

3-in-1 profiling

Capture rheological Tg and Tm plus mechanical damping in one sub-zero test on pellets, with no sample preparation.

About the Premier ESR with Sub-Zero™ Technology

Precise Tg measurements below freezing

Our encapsulated sub-zero rheometer applies oscillatory shear to polypropylene samples below freezing, delivering precise Tg measurements in minutes and replacing time-consuming DSC and DMA routines.

About the Study

Developed by Alpha’s application experts

Unal Yilmazoglu, Senior Scientist and Global Application Team Leader, and Richard Hanzlik, Market Development Manager, developed this study to find a definitive way to measure Tg accurately and efficiently across polypropylene grades. The study used the Premier ESR®, which complies with ASTM D7750.

Unal Yilmazoglu

Unal Yilmazoglu

Senior Scientist, Global Application Team Leader

Richard Hanzlik

Richard Hanzlik

Market Development Manager

Download the White Paper

Streamline your PP Tg testing

See how Alpha Technologies uses sub-zero rheometry to deliver rapid, highly sensitive Tg measurements that streamline QC and R&D workflows.